Thanks all for the suggestions and help with this, all sorted now. Turned out to be a combination of:
1. Faulty battery; not helped by:
2. Low output from the alternator (13v), so the battery was not being charged during trips; and:
3. Dodgy earth connection to the voltmeter.
I now have a new battery, recondition alternator, a good earth, and one of those ctek 'smart' chargers to try and keep it good condition.
Cheers
Steve