Bit of an update to this. Since getting back from GNW I've found that after the car is left for a couple of days all is good on starting; charging light on, then off, volt meter at normal. However, after driving for 5 minutes or so (this used to be around 30 minutes) the volt meter drops, and after switch off the charging light does not come back on, ie it is dead.
So, found my multimeter and put in a new 9 volt battery (£5!). 12 volts across the battery then 13.8 on start up, BUT, after that 5 minute drop on the voltmeter it's down to 11.2 and moving to the alternator itself I found pretty much the same reading. So, my bet now is on the voltage regulator on the alternator, or some other alternator fault.
I take back what I said about Varta batteries!
As for the breakdown, well, the earth lead from the battery was only finger tight, which must have really exacerbated the drain off of power. Lucky I got home at all........